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Nilanjan Bhowmick AIR 3, CSIR NET (Earth Science)
- IIT JAM
- Chemistry (CY)
Please provide the complete notes of types of isomerism in coordination compound
please provide the complete notes of types of isomerism in coordination compound
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Boddu rama krishna
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There are four types of structural isomerism: In ionisation isomerism, the isomers result in different ions in solution although they have the same composition. This type of isomerism occurs when the center ion of the complex is also a potential ligand. For example, pentaaminebromidocobalt(III) sulphate [Co(NH3)5Br]SO4 is violet and in solution gives a precipitate with barium chloride, confirming the presence of sulphate ion. Pentaaminesulphatecobalt(III) bromide [Co(NH3)5SO4]Br on the other hand, is red and tests negative for sulphate ion in solution. It gives a precipitate of silver bromide (AgBr) with silver nitrate (AgNO3). In solvate or hydrate isomerism, the isomers have the same composition but differ with respect to the number of solvent ligand molecules as well as the counter ion in the crystal lattice. For example [Cr(H2O)6]Cl3 is violet colored, [Cr(H2O)5Cl]Cl2·H2O is blue-green, and [Cr(H2O)4Cl2]Cl·2H2O is dark green. Linkage isomerism occurs with ambidentate ligands that can bind in more than one place. For example, NO2 can bind to a metal at either the N atom or an O atom. In coordination isomerism, both positive and negative ions of a salt are complex ions and the two isomers differ in the distribution of ligands between the cation and the anion. For example, [Co(NH3)6][Cr(CN)6] and [Cr(NH3)6][Co(CN)6].
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Priyanshu kumar Best Answer
https://drive.google.com/file/d/1hYqzXXOV7QxOb5Bja5o_DwwhpGwwt7Dm/view?usp=drivesdk check this
check this also https://chem.libretexts.org/Bookshelves/General_Chemistry/Map%3A_General_Chemistry_(Petrucci_et_al.)/24%3A_Complex_Ions_and_Coordination_Compounds/24.04%3A_Isomerism
download from the above link
Sir pls provide different from these
okk wait
https://drive.google.com/file/d/1hueZL64g8TvVtvrMQSufm8FY20Df4PLC/view?usp=drivesdk check this note
If you want more then tell
sir some pages r not clear....... if u have handwritten notes of this topic pls provide
now i haven't but this much is sufficient for this topic...
Ok sir