Vaishali posted an Question
February 01, 2022 • 03:20 am 15 points
  • CSIR NET
  • Chemical Sciences

6. which of the following complexes do you expect to be paramagnetic and to have an orbital contribution to the magnetic moment? [gate 2015] (1) [fe(en):]2 (2)

6. Which of the following complexes do you expect to be paramagnetic and to have an orbital contribution to the magnetic moment? [GATE 2015] (1) [Fe(en):]2 (2) [Fe(CN):]4 (3) [Mn(F)6]2 (4) [Mn(CN):12 7 dc

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    Lingareddy 1 Best Answer

    t2g 4 eg2 due to t2g unsymmetrical filled it shows orbital contribution

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    but it is diamagentic

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    Lingareddy 1

    option C

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    option a is the answer ... in (c) t2g is symmetrically filled then how orbital contribution can takes place

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    ya u correct i did not saw orbital contribution

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