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Nilanjan Bhowmick AIR 3, CSIR NET (Earth Science)
Rahul kumar
CRYSTALLIZATION SEQUENCE OF COMPOSITION X: As a liquid of composition X is cooled, nothing will happen until the temperature is equal to the liquidus temperature. At this point crystals of A begin to precipitate out of the liquid. As the temperature is further lowered, the composition of the liquid will change along the liquidus toward the peritectic (P), and the crystals forming from the liquid will always be pure A until P is reached. At the temperature of the peritectic, note that three phases must be in equilibrium, A, liquid, and C. At this point some of the crystals of A react with the liquid to produce crystals of C. The reaction that takes place can be written as follows: A + Liq= C After all of the liquid is consumed by this reaction, only crystals of A and C will remain. The proportions of A and C in the final crystalline product can be found by applying the lever rule. CRYSTALLIZATION SEQUENCE OF COMPOSITION Y: Since composition Y lies between C and B, it must end up with crystals of C and B. If such a composition were cooled from some high temperature where it is in the all liquid state, it would remain all liquid until it reached the liquidus temperature at about 1600. At this temperature crystals of A would begin to precipitate and the composition of the liquid would begin to change along the liquidus toward the peritectic, P. At P, all of the A previously precipitated would react with the liquid to produce crystals of C. After this reaction has run to completion, and all of the previously precipitated A is consumed, there would still remain some liquid. With decreasing temperature, more crystals of C would form, and the liquid composition would change along the liquidus toward the eutectic, E. At E crystals of B would begin to form, the temperature would remain constant until all of the liquid was used up, leaving crystals of B and C as the final solid. Note that because composition Y lies very close to the composition of pure C, the final crystalline product would consist mostly of C with a very small amount of B.
Nice Explaination