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16 products (p) in the following reaction is 0 rh(oac product (p) -nh n2 our cobn nh =o=o (a) c co2bn o o (d) (c) o cho 0
16 Products (P) in the following reaction is 0 Rh(OAc Product (P) -NH N2 OUR cOBn NH =O=O (a) C CO2Bn O O (d) (c) O CHO 0
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Priyanshu kumar
Rh2(OAc)4 is a very useful catalyst for two-component-cycloaddition as well as three-component 1,3-dipolar cycloaddition reactions. On treatment with catalytic rhodium(II) acetate, cyclic diazoamides and diazoamines furnished the corresponding cyclic enamides and Z enamines, repectively
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option A is correct Check the uses of Rh2(oAc)4
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Dinesh khalmaniya 1
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option A here carbene is formed will insert to N-H bond. concept- Carbenes can insert into bonds such as O-H and N-H bonds. The mechanism involves addition of the oxygen lone pair into an empty p-orbital on the carbene, followed by proton transfer to generate a neutral molecule from the first formed zwitterion (or ylid).
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