profile-img
Sourav posted an Question
July 21, 2020 • 16:24 pm 30 points
  • IIT JAM
  • Chemistry (CY)

17. the correct basic strength order of the following anion is: (a) ch3-ch2> nh2 > ch2=ch >ch=c> oh >f (b) nh2> ch3-ch2> ch:=ch> ch=c>f>oh (c) ch3-ch2 > ch2=ch

1 Answer(s) Answer Now
  • 0 Likes
  • 4 Comments
  • 0 Shares
  • Suman Kumar

    Q 19 option B is correct

    eduncle-logo-app

    but in ans, option A is given as answer

    eduncle-logo-app

    https://youtu.be/69AyGv7dL2Q

    eduncle-logo-app

    See this.

    eduncle-logo-app

    Option B is right, Sourav.

    eduncle-logo-app

    Given answer is wrong.

    eduncle-logo-app

    sir according to the video you shared, option A is correct given on YouTube

    eduncle-logo-app

    Yes A is correct

  • comment-profile-img>
    Dinesh khalmaniya 1

    Option C

    eduncle-logo-app

    NH2 more basic than CH2?

    eduncle-logo-app

    yes

    eduncle-logo-app

    you know conjugate base of weaker base is strong acidic

    eduncle-logo-app

    conjugate acid of weaker base is more acidic

    eduncle-logo-app

    yes

    eduncle-logo-app

    so arrange them in acidity order. weaker acid will give strong base. i.e., basicity order of CB will be reversed of acidity

    eduncle-logo-app

    got it??

    eduncle-logo-app

    i have to first convert them. into acids by adding hydrogen?

    eduncle-logo-app

    yes

    eduncle-logo-app

    wait I'm sending full Sol

    eduncle-logo-app

    option A is correct

    eduncle-logo-app

    how

    eduncle-logo-app

    I've solved check it??

    eduncle-logo-app

    what's answer given in you booklet??

    eduncle-logo-app

    i didn't get any soln sir..ans in booklet is C

    eduncle-logo-app

    there is something problem in this app

    eduncle-logo-app

    may be later it can fix

    eduncle-logo-app

    option A or C?

    eduncle-logo-app

    match the option according to this

    eduncle-logo-app

    acidity of C2H2 is greater than NH3 so NH2- will be strong Base

    eduncle-logo-app

    option C

    eduncle-logo-app

    sorry by mistake i say A, it's C

    eduncle-logo-app

    in starting i say option C. it's correct

    eduncle-logo-app

    sir plz ans rest qs

  • Suman Kumar best-answer

    Wait Sourav

    eduncle-logo-app

    Option C is correct

    eduncle-logo-app

    This is acidity order

    eduncle-logo-app

    Hence it's reverse will be the basicity

    eduncle-logo-app

    Now you ask your doubts.

    eduncle-logo-app

    Sorry for the confusion.

    eduncle-logo-app

    See here basicity will be defined by the stability of anion. More stable the anion less will be the basicity

    eduncle-logo-app

    Acidity is determined by the stability of the anion formed. Hence relate the two

    eduncle-logo-app

    Sourav got it

    eduncle-logo-app

    please respond

    eduncle-logo-app

    i cant understand how NH2 more basic than CH2

    eduncle-logo-app

    Now you tell me -ve is stable where

    eduncle-logo-app

    More stable is the negative charge less is the basicity

    eduncle-logo-app

    negative charge more stable on nitrogen?

    eduncle-logo-app

    Right Sourav. Hence what will be the basicity then Sourav

    eduncle-logo-app

    and between C2H and NH2?

    eduncle-logo-app

    There is theory eletronegativity jump rule I suppose which says sp carbon is more eletronegative than sp3 nitrogen. Similarly sp nitrogen is more eletronegative than sp3 oxygen.

    eduncle-logo-app

    So sp C2H is more eletronegative than sp3 NH2-

    eduncle-logo-app

    sir i need ans for rest qs

whatsapp-btn

Do You Want Better RANK in Your Exam?

Start Your Preparations with Eduncle’s FREE Study Material

  • Updated Syllabus, Paper Pattern & Full Exam Details
  • Sample Theory of Most Important Topic
  • Model Test Paper with Detailed Solutions
  • Last 5 Years Question Papers & Answers