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Nilanjan Bhowmick AIR 3, CSIR NET (Earth Science)
Priyanshu kumar
According to fundamental concept of organic chemistry 6 hyperconjugation of a molecule is considered to be as same as a equivallent canonical structure for molecular or in this case carbocation stabilisation. So as in this case tert butyl carbocation has 3 hyperconjugation extra thus tert butyl carbocation should be stable than allylic carbocation.
i dont get it can u plz explain again
means allylic me 2 equivalent canonical structure hai jo 6 hyperconjugative structure se same hote hai..now tert butyl carbocations is 3 hyperconjugative structure more stable so more stable
and also tert butyl carbocation is more stable as +H effect and +I effect of methyl group is there
okay thank u very much