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Sourav posted an Question
July 21, 2020 • 06:17 am 30 points
  • IIT JAM
  • Chemistry (CY)

25 which of the folowing is most polar (a) (b) () (d)

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  • Suman Kumar best-answer

    See azulene exist in this form. Always generation of charge makes the compound most polar.

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    So it is highly polar

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    sir, i have problem in how to approach these qs. How to do charge separation by myself and proceed.

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    I order to make the ring aromatic charge separation occur.

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    Same is happened in Quasi aromatic compound.

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    Quasi aromatic compound are also highly polar

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    Did you get this Sourav

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    Priyanshu kumar

    option C both the rings are already aromatic...so after charge separation aromaticity breaks

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    option B structure same case...charge separation is already present and both rings are aromatic

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    Priyanshu kumar Best Answer

    option B is here most polar... Concept is polar means dipole moment means charge separation...so after charge separation the formed structure is stable then it is most polar....See the option B is azulene after charge separation both the rings formed are aromatic...

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    In option A structure both the rings are anti aromatic

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    got this sourav??

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    what do you mean by charge separation.. can you explain it with a diagram on the options

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    see this is charge separation means positive n negative charge

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    got sourav??

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    i guess charge separation is done by resonance and if so can we bring positive charge on the small ring and negative charge on big one?

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    positive charge on big one and negative on small one

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    sir i guess the small ring has 4 pie electrons?

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    in case of azulene you are talking about

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    yes

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    see here it is done charge separation like this just to know about charge separate but actually it happens like that one of double bond is common to both the rings so that smaller rings gets 6 pi electrons and large ring too get

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    both become aromatic

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    sir how to approach this type of. qs? i can't imagine how to separate charges and then think about the structure

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    practice goc questions and ques by ques the concept you are missing you came to know...then relate this type with aromaticity concept...so overall practice more n more questions of goc

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    sir is there any material to learn about these concepts of how to deal with charge separation? can you help me out?

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    wait i'm checking if it available to me...i will put it here you can check it later

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