Payal posted an Question
October 13, 2020 • 20:25 pm 30 points
  • IIT JAM
  • Chemistry (CY)

A reaction is at equilibrium in a closed rigid vessel at constant temperature when (a) as 0 (b) ah 0 (c) ag0 (d) a 0

A reaction is at equilibrium in a closed rigid vessel at constant temperature when (A) AS 0 (B) AH 0 (C) AG0 (D) A 0

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  • Suman Kumar best-answer

    option D is correct

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    At constant temperature & volume delA is zero

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    Here volume is zero as vessel is closed

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    Priyanshu kumar Best Answer

    Option D del A=0 Explanation:- deltaG=0 is the equilibrium condition at constant T and P. In a sealed rigid container, though, the system is not at constant P so instead one must use the Helmholtz free energy, A. At constant T and V the equilibrium condition is that deltaA=0. G=E+pV-TS and A=E-TS

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