Niharika Kalita posted an Question
May 05, 2020 • 04:35 am 9 points
  • IIT JAM
  • Chemistry (CY)

At 273k measurements on ar gave b=-21.7cm3mol-1 and c=1200cm6mol-2,where b and c are 2nd and 3rd virial coefficient in the expansion of z in the powers of 1/vm.

At 273K measurements on Ar gave B=-21.7cm3mol-1 and C=1200cm6mol-2,where B and C are 2nd and 3rd virial coefficient in the expansion of Z in the powers of 1/Vm. Assuming that the perfect gas law holds sufficiently well for the estimation of 2nd and 3rd terms of the expansion, calculate the compression factor of Ar at 100atm and 273K. From the result, estimate the molar volume of Ar under these conditions. Please explain in detail.

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