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Divya posted an Question
September 09, 2020 • 23:24 pm 30 points
  • IIT JAM
  • Chemistry (CY)

Basicity order

Sir with the help of ortho effect how can we explain basicity order?

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  • Suman Kumar best-answer

    2>1>4>3

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    3rd one is least basic due to ortho effect i.e Steric inhibition of protonation

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    Priyanshu kumar Best Answer

    3rd one is least basic

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    benzylamine is more basic than aniline

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    so order 2>1>4>3

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    sir 2nd compound still doubt

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    benzyl amine is more basic here...

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    lone pair is not in resonance...but in aniline lone pair on nitrogen is in resonance with benzene ring...which is not available for donation....

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    see for aniline and benzamide

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    now got this divya??

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    ok sir

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    thank you

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