Simun Mishra posted an Question
August 29, 2020 • 01:29 am 30 points
  • IIT JAM
  • Chemistry (CY)

Can u pls explain me the mechanism of this 2 reaction?

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    Dinesh khalmaniya 1 Best Answer

    yes, wait

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    yes sir and sir pls tell me R2CuLi react with compounds like

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    check this https://www.masterorganicchemistry.com/2016/02/05/gilman-reagents-organocuprates-what-theyre-used-for/

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    first read this so you can understand how this reagent attack

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    after that you will be able to understand these two reaction

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    I have already read this sir

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    so still doubt?

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    R2CuLi attack towards less sterically hindered site

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    here in 1st example SN2 occur

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    yes sir pls tell me this reagent react with which compounds

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    while in 2nd conjugate addition

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    yes, wait

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    I'm explaining it giving you some examples

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    but sir galiman reagent do machial addition but here their is no alpha bita positions

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    check it

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    yes, simun in 2nd there is Michel addition

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    just like unsaturated carbonyl

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    actually it is soft reagent so attack on soft side

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    got it?

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    yes sir I m confused in first one

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    what's your confusion?

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    and sir what is soft and hard reagent and what is hard and soft side

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    have checked micheal addition notes in booklet where mentioned everything about it. it is based on HSAB principal

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    you if you need i can send HSAB

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    no sir in jam booklate their is not given this

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    yes sir pls send me

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    wait

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    go through this link https://www.adichemistry.com/inorganic/cochem/hsab/hard-soft-acid-base-theory.html

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    sir can u pls send me Michael addition from Csir net booklate

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    yes, I'll send you

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    tqq sir after I m reading it I will asked about this question further

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    yes, sure.

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    sorry net is slow this time I'll send you later

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    yes sir I m waiting for it

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    don't worry I'll send you soon😊

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    sir pls tell me this reagent react with compounds like

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    and sir pls tell me what's the picture trying to say I can't understand it

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    it's trying to say which compounds show cleavage of C-X bond 8n presence of Gilman reagent

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    this reagent is not given in the CsIR booklet

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    sir I m asking for Michael addition note of csir net

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    and the reagent react with compounds like

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    it react with carbonyl, epoxides etc

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    it is nucleophilic reagent so just like other reagent can react with carbonyl or epoxides and gives SN2

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    sir acid cl also react with this na

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    and sir what is the mechanism when this reagent react with epoxide

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    sir can u pls tell me this

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    Simun, I'm very busy this time so i couldn't reply. I'll be back with solution

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    yes sir I m waiting

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    check the reactions given by R2CuLi and examples

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