Comprehension (q. 114-116) study the two photochemical reactions and answer the question at the end. for the overall reaction between a and b to yield c and d,

Comprehension (Q. 114-116) Study the two photochemical reactions and answer the question at the end. For the overall reaction between A and B to yield C and D, two mechanisms are proposed: LA+B AB C+D, k=1x 10 Ms IL. A A E, k=1x 104s E+B C+D, k-1x 1010 Ms (species with are short-lived) 114. Rate according to mechanismI when concentration of each reactant is 0.1 M will be: (a) 1 x 10 Ms(b)1x 10- Ms 115 Rate according to mechanisth lI when concentration of each reactant is 1 M will be: (c)1x 10 Ms (d) 1x 10 Ms 115 b) 1x 100 Ms (c) x 106Ms At what concentration of B, rates of two mechanism are equal: (a) 1 x 10 Ms (d) 1x 10-10 Ms 116 (a) 1 M (b) 5 M (c) 7M (d) 10 M