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Nilanjan Bhowmick AIR 3, CSIR NET (Earth Science)
Dinesh khalmaniya 1
Here Aniline behave as nucleophile and reagent is NO+ which is an electrophile. so simply we can say it is an Electrophile substitution reaction because H atoms substitution takes place after attack of NO+. Mechanism-- The first step is formation of a new N–N bond, which occurs through attack of the nitrosonium ion by the aromatic amine (Step 1). This is followed by two proton transfers from nitrogen to oxygen (Steps 2 and 3) accompanied by reorganization of the pi bonding framework [forming N–N (pi), breaking N–O (pi) ]. The final step is formation of the nitrogen-nitrogen triple bond accompanied by expulsion of water (Step 4).