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Sourav posted an Question
October 07, 2020 • 06:06 am 30 points
  • IIT JAM
  • Chemistry (CY)

Doubt in a and b

1 Answer(s) Answer Now
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    Priyanshu kumar Best Answer

    In A order will be 2<1<3 and in b order will be 3<1<2 ...whats your doubt?

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    in a how 3 more stable than 1?

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    H is attached to sp hybridised carbon atom..so most acidic here

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    but after removing 1 H, there will be reso stablised na?

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    in 3 there is no reso

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    yes so 1 is more than 3 but here in 2 there is highest electronegativity so it readily release H+

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    i didnt get what you are saying sir

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    so i did numbering wrong so confusion...

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    what will be the answer

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    according to me for A, ans should be 2<3<1

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    Sourav 3 is most acidic as yha highest electronegativity hai so deprotonation bahut fast hoga then 1 reso stabilised then 2

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    Maine bola bhi koi rigid comparison nhi hota acidity or basicity decide krne me

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    but sir, reso stabilization jyda hota hai na electronegativity comparison se

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    yes you think is right...

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    im confused when to use what

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    sourav rigid nhi rhta hai khaskr acidity or basicity comparison me ....sometym pka or pkb differ...so confusion aate hai

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    but generally rule follow hote hai

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    sir ye stable kyun nahi hai

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    sir u there?

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    typing sourav🙂

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    According to me may be due to two factors as after deprotonation no resonance stabilised..and .after protonation oh2+ leaving group carbocation forms which is destabilized by - I effect of oxygen of och3 grp

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    it is saying that that molecule is unstable sir

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    if doing deprotonation and protonation, it is unstable, then the molecule shud be itself stable na

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    sourav unstable means it is reactive and och3 is good leaving group oh2+ is also good leaving grp...so it readily removes means reactive

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