Shifana Asked a Question
October 22, 2020 11:43 pmpts 30 pts
why epoxidation is not taking place??????....,...........
  • 2 Answer(s)
  • Shares
  • Narayanarao gundoju
    in Baeyer- viliger oxidation if you use acidic medium peoxides or alkylsilylperoxides or MCPBA, lactone and also steric carbonyls give lactone.
    Likes(0) Reply(0)
  • Suman Kumar
    There are two reasons. ist Carbonyl is more reactive 2nd since it is a bridging compound so baeyer villiger oxidation give some relaxation by increasing the size of the ring
    Likes(0) Reply(0)
  • Priyanshu kumar thankyou
    m-cpba attacks alkene to form epoxides but here it proceeds through baeyer villeger oxidation. Here m-cpba attacks at carbonyl group as carbonyl group is more reactive than alkene....
    Show more
    • cropped5869897539884645518.jpg
    Likes(0) Reply(0)
  • Dinesh khalmaniya thankyou
    because here reactivity of carbonyl is more than alkene. it accept H+ from peroxide. check the complete mechanism.
    • cropped1597990844582880322.jpg
    Likes(0) Reply(0)
Head Office :
MPA 44, 2nd floor, Rangbari Main Road,
Mahaveer Nagar II, Kota (Raj.) – 324005

Corporate Office:
212, F-1, 2nd Floor, Evershine Tower,
Amrapali Marg,
Vaishali Nagar, Jaipur (Raj.) – 302021

All Rights Reserved ©