Shweta Thakur posted an Question
August 02, 2020 • 04:05 am 30 points
  • IIT JAM
  • Chemistry (CY)

Here ...can i say that in axial( 2conformer)..that all torsional ,vanderwall,steric and angle strain exist ....

2 at hoval, s euw Heu nepudyy njxkdkgckc. clfjkfjjg

2 Answer(s) Answer Now
  • 0 Likes
  • 2 Comments
  • 0 Shares
  • comment-profile-img>
    Ashutosh singh best-answer

    Dear student, This is a classic example of 1,3-diaxial interactions which makes this unstable. And yes, there will be steric strain due to presence of Hydrogen at 3rd position and H of methyl group. Since, you have drawn the chair confirmation, there's no angle strain pronounced because all the angels will be near the value of tetrahedral angle. Note - Steric strain and 1,3-diaxial interactions are main reason behind the unstability.

    eduncle-logo-app

    Shweta, I don't think Vanderwaals strain is right term. It's steric strain, actually.

    eduncle-logo-app

    And as soon as the ring flips, this axial bonds become equitorial, which eliminates the possibility of 1,3 diaxial interactions which is why we say equitorial bonds are more stable than axial ones.

    eduncle-logo-app

    thankyou sir 😊

  • comment-profile-img>
    Priyanshu kumar Best Answer

    see shweta

    cropped262960431821871127.jpg
    eduncle-logo-app

    See the position how can you identify cis and trans....and due to 1,3diaxial interaction it is less stable ....In eqautorial no such interactions is pronounced....And steric strain due to H at 3rd pos. and Methyl group..

    eduncle-logo-app

    got this shweta??

    eduncle-logo-app

    can we also say that there is vanderwalls string between groups

    eduncle-logo-app

    No here in chair form steric strain and diaxial interaction is more pronounced

    eduncle-logo-app

    ok

    eduncle-logo-app

    thankyou sir 😊

    eduncle-logo-app

    welcome shweta😊

    eduncle-logo-app

    I have sent one question in mail

    eduncle-logo-app

    okk let me see

    eduncle-logo-app

    sir for 1,3 u have written a ,a or e,e cis... ...trans ni aana chagiye

    eduncle-logo-app

    yes shweta a,a and e,e cis and a,e and e,a for trans for 1,3 position

    eduncle-logo-app

    ok sir

    eduncle-logo-app

    ye yaad nhi rhe na...to phle chair conformation bna lena fr axial equatorial bna lena fr numbering kr dena...ab jo bhi substituted diya rhe chahe 1,2 1,3 1,4 check krna..axial equatorial position..agr same side rha to cis opposite rha to trans

    eduncle-logo-app

    yes sir ye concept clear hai poora

    eduncle-logo-app

    good 👍

    eduncle-logo-app

    but sir I didn't get how a,e or e,a is cis

    eduncle-logo-app

    and e,e trans

    eduncle-logo-app

    dekhne main to sirf a,a trans lgte hai

    eduncle-logo-app

    1,3 ke liye kya shweta??

    eduncle-logo-app

    shweta bs position pe check krna ....up up rha to cis up down rha to trans...bs ye check krna equatorial or axial

    eduncle-logo-app

    I a talking about this

    eduncle-logo-app

    dekho shweta

    eduncle-logo-app

    this also

whatsapp-btn

Do You Want Better RANK in Your Exam?

Start Your Preparations with Eduncle’s FREE Study Material

  • Updated Syllabus, Paper Pattern & Full Exam Details
  • Sample Theory of Most Important Topic
  • Model Test Paper with Detailed Solutions
  • Last 5 Years Question Papers & Answers