Shweta Thakur posted an Question
January 11, 2021 • 00:19 am 30 points
  • IIT JAM
  • Chemistry (CY)

Here oxygen of phenolic group will attack or oxygen of carbonyl on alcl3 plz tell .... aic

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  • comment-profile-img>
    Dinesh khalmaniya 1 Best Answer

    Here O of phenolic group will attack because it is more nucleophilic than carbonyl O. Here phenolic O has sp3 hybridisation and carbonyl O has sp2 hybridisation. more the %s less is the nucleophilicity

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    sir but phenol oxygen is in resonance with benzene

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    sir plz answer

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    wait shweta ...

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    actually sweta, lone pair of O can resonate with carbonyl O but isse phenolic O pr positive charge aa jayega so resonance favorable nhi hoga

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    reference. Shweta reference k according phenolic o attack krega. google pr or bhi examples he jisme carbonyl se attack show kr rkha he pr vo authentic nhi he

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    thanku

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    🙏🙏

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    sir

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    in one video intramolecular and intermolecular both mechanism they have done for fries

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    so which is important

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    https://youtu.be/Pmv5HYICotY

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    this

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    sir

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    wait

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    one more thing u have sent me the notes of fries

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    yes

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    there you have abstract 1 chlorine from aluminium chloride

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    but I have not done like this in the last step only I remove alcl3

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    apko kha doubt he mechanism me, shi to he

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    .m

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    many ye

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    sir. doubt ni hai bs ik cheek confirm krni hai

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    wait I'll reply

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    sir alcl3 main se cl ko remove krna jroori hai

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    Mene remove nahi kiya please check my mechanism

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    and please check that video there they have done both intramolecular and intermolecular mechanism

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    does I need to remember both

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    and I have got this reason

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    yes, it's correct I've given same reason

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    and sir baaki doubts Ka bhi answer de do

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    ha me dekh rha hu.. sare double clear kruga

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    ok

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    apki mechanism bhi correct he by AlCl3 pr - charge ayega

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    ap bs intermolecular mechanism dhyan rkho... koi jrurt nhi he confused hone hi.. apne jo mechanism di vo correct he bs O pr + or AlCl3 pr - charge ayega

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    thanku so much

  • comment-profile-img>
    Priyanshu kumar best-answer

    O of phenolic group will attcahed to Alcl3

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    why

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    first attack between C=O group then migration leads to attach with phenolic O

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    check this

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    reason sir carbonyl carbon pe kyun attack hua

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    carbonyl oxygen is nucleophilic centre due to polarised carbon oxygen double bond

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    https://youtu.be/Pmv5HYICotY see this video

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    sir video main phenolic oxygen ke through Kiya

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    sir

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    both way you can do ..both are correct

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    either first attack with carbonyl oxygen and then migration leads to attached with phenolic O...or attach with phenolic O and removal of acylium ion

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    see this reference too

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    sir ye app bhot hang hota

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    reply Sare remove ho jaate Hain

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    haa bahut fast internet pe achha chalta hai ye app

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    client show karne lagte hai

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    sir

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    sir

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    sir

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