Simun Mishra posted an Question
July 25, 2020 β€’ 00:23 am 30 points
  • IIT JAM
  • Chemistry (CY)

How can ring expenstion possible ?

2 Answer(s) Answer Now
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  • 6 Comments
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  • comment-profile-img>
    Dinesh khalmaniya 1 Best Answer

    check this mechanism

    cropped9113100299541407369.jpg
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    I m checking sir

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    okay πŸ‘πŸ˜Š

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    but sir this ring expansion last steep I can't understand

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    in last step H removed from positive charge O. as positive charge O is less stable due to high EN

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    no sir not this the steep where u convert 5 membered ring to 6 membered

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    yes wait

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    sir always 5 membered ring expansion result to 6 membered ring na ?

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    and sir how to know in which case ring explanation takes place

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    in all cycloalkanone ring expansion takes place.

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    just like it. compair it with mechanism which I've sent

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    got it now?

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    sir can u give me example of any cycloalkanone any ring expansion and its condition in which ring expansion takes place

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    see if carbony group is out of ring than no rearrangement if carbonyl group is in the ring than ring expansion takes place

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    just like it

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    got it now😊?

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    ohhh yes sir

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    πŸ˜ŠπŸ‘πŸ‘

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    I m little bit got it now I m try to do examples then if any problem told u πŸ˜ŠπŸ™

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    yes then if you have any problem you can share with me 😊

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    ok sir tq sir

  • comment-profile-img>
    Dinesh khalmaniya 1

    you have to insert O between carbonyl carbon and alpha Carbon atom

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    Dinesh khalmaniya 1

    it is baeyer villiger oxidation so Oxygen insertion takes place

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    like this

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    I know this sir I can't do the mechanism of this reaction ..

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    I can't know how the ring expansion takes place

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    okay wait..

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    yes sir

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    check the mechanism which I've send you

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