Simun Mishra posted an Question
July 15, 2020 • 03:27 am 30 points
  • IIT JAM
  • Chemistry (CY)

How to know which is strongest base in water ?

1 Answer(s) Answer Now
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  • 6 Comments
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  • Suman Kumar

    I think pyrrolidine is more basic.

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    You just accept for now. I will definitely give reason. Just give me time.

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    ok pls tell me

  • comment-profile-img>
    Priyanshu kumar

    prrrolidine has slightly more basicity than piperidine..so option B is right

    cropped6701250476518678938.jpg
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    got it simun??

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    here both option B and D have nearly same basicity but stabilisation is more in 5 membered ring than 6 membered ring

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    can u give theoretical or any pdf or video solution of goc questions which u send to me

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    can u ....pls ?...

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    wait let me check it out

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    https://youtu.be/quuBjmGktmM check it simun

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    https://youtu.be/_psRXrDF12g

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    https://youtu.be/d1FysLiS48E

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    please mark the answer if it really helps u😊🙏

  • comment-profile-img>
    Dinesh khalmaniya 1

    explanation

    cropped6503242671860855558.jpg
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    Simun check the explanation

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    can u explain me about structure no 3

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    yes, why not. wait..

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    but stabilization is more in 5 membered ring then 6 membered ring

  • comment-profile-img>
    Dinesh khalmaniya 1

    strongest base are those whic can easily release lone pair of electrons

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    wait I'm explaing

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    I know but here ans is b

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    yes, actually there are little bit different in pka values so practically ans is b but conceptually ans should be d

  • comment-profile-img>
    Dinesh khalmaniya 1

    option D

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    but ans given is b

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    wait I'm checking

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    wrong answer given

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    reference source

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    now let me explain

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    please check the explanation

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    got it???

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    but here ask strongest base in water

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    yes, we can use water. Basicity will not affect

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    means normal basicity rule is apply here water can't effect its basicity

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    yes, water is solvent

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    what things will effect the basicity of a compound

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    wait I'm providing some images

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    check here in 1st image , factors are given which affects the basicity

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    here ring size also given as a factor, as ring size increase basicity increase

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    but 5 membered ring is stable then 6 membered ring

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    yes, but here we are not taking stability, we are talking about basicity. if after accepting H Conjugate acid is stable then compound is most acidic

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    still I'm trying to conclude that why 5 member ring is more basic than 6 members because data obtained form the internet are different. some where basicity of 6 member amine is given more than 5 member. so wait if i get some references I'll sure share with you

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    ok pls try to solve this with explanation

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    yes, wait..

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