Simun Mishra posted an Question
August 10, 2020 β€’ 18:46 pm 30 points
  • IIT JAM
  • Chemistry (CY)

If in aniline in ortho position oh and nh2 is present then ortho effects works or not ....?

2 Answer(s) Answer Now
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    Priyanshu kumar best-answer

    Yes simun...ortho effect works here

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    In these case intramolecular H bonding occurs

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    but sir in a video given that in this case when OH and NH2 in ortho position then reverse of ortho effect makes it more basic

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    yes simun due to electron donating tendency +R effect of Oh and Nh2 group it increases electron density ...so increases the basicity

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    ok sir

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    simun here ortho effect also works but due to strongly activating tendency of OH and NH2 group,it dominates and increases its basicity

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    Dinesh khalmaniya 1 Best Answer

    yes, will work if any group attached to ortho position

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    but sir in a video given that If OH and NH2 present in ortho position then ortho effect increases it basicity

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    wait..

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    ok sir

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    sir what is correct

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    sorry simun, i was busy now I'll check

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    yes simun, due to intramolecular H bonding, here H bonding is dominated over ortho effect so basicity of ortho amino phenol will be high

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    it's ok sir yes sir tqq so much sir ..only this 2 OH And NH2 na

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    yes

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    ok sir πŸ™πŸ™and sir I m very much confused in the name reaction

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    the question of this is difficult for me to identify ....?

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    what's your confusion??

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    are you solving problems regularly??

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    no sir I can't start question of reaction mechanism

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    then what's doing now a days?

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    I have done revision of goc and study some name reaction after 2 days it will be complete

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    then the pericyclic reaction and reagent are also their which I have to study

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    due to health issues I can't give much time for study so

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    Simun, first health and then everything

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    yes sir but I have to complete organic chemistry till September ..πŸ˜”

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    after recovering your health you can try to do your best πŸ‘πŸ‘

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    yes sir i m fine now ..and sir my semester are also in jan so i have to study for that also

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    yes, you need good score in semester also. so along with jam, prepared for it also

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    yes sir and I m giving jam in 2022 so I some time also ..for jam

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    πŸ‘πŸ‘πŸ‘

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    ok sir πŸ˜ŠπŸ˜ŠπŸ™πŸ™

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