Anand posted an Question
September 25, 2020 • 18:10 pm 30 points
  • IIT JAM
  • Chemistry (CY)

If nacl has an fcc structure, then why is its coordination number 6 instead of 12?

If NaCl has an FCC structure, then why is its coordination number 6 instead of 12? is it a right diagram?

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    Priyanshu kumar Best Answer

    fcc is packing of an element. for, NaCl, it s not simply Na or Cl its a combination of both. in NaCl, each Na+ is surrounded by 6 Cl- and vice versa. so, coordination number is 6. Each Na ion has 12 Na second-nearest neighbors, and each Cl ion has 12 Cl second-nearest neighbors.

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    Metallic crystal in FCC has coordination number 12. NaCl is an ionic crystal having FCC structure in which coordination number of both cation and anion are 6.

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    can u give me str of nacl

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    see

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    is is right

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    yes see the image....focus on each cation and anion

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    in diagram you have given, it is difficult to see voids, na is betn the voids na

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    for coordination number you have to check na...see each Na+ is surrounded by 6 Cl- ions and vice versa

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    do chlorine atoms touches to each other or not?

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    as well as na atoms touch each other?

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    cl to cl ans na to na

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    The crystalline structure of NaCl is face-centred cubic. The total number of ions present in one unit cell of sodium chloride lattice is 8. It includes 4 Na+ ions and 4 Cl− ions. There are 8 Cl− ions at 8 corners of fcc unit cell (each one contributes one eigth to unit cell) and 6 Cl− ions at 6 face centres  (each one contributes one half to unit cell). Total number of Cl− ions in the unit cell =8×81​+6×21​=1+3=4 Na+ ions occupies octahedral voids. There are 4 octahedral voids in fcc unit cell. Thus, there are 4 Na+ ions in fcc unit cell.

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    this is explanined for unit cell

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    when coordination number finding see the image you clearly see how 6:6 CN is there

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    do Na atoms touch each other or not in this structure?

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    Na to na?

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    no sodium ion in center touched by 6 cl ion

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    see this one , is it right?

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    yes this is right...bdw these are 3d type crystal structure so better you see ball and stick model of this...may be available on YouTube

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    is this right for nacl?

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    for this co ordination no is 12

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    so im confused

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    dear why you checking common check for each ion individually and so i told na for this see model of this

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    https://youtu.be/v8g3CK5kke0 check

  • comment-profile-img>
    Dinesh khalmaniya 1 best-answer

    because Na is surrounded by 6 Cl- ions and Cl- is surrounded by 6 Na+ so cordinatio ratio is 6:6

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    check this link for more details http://www.questtutorials.com/media/static/xii/chemistry/02_The%20Solid%20State/04_Structure%20of%20simple%20ionic%20compounds.htm

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