Parvathy posted an Question
January 27, 2021 • 03:29 am 30 points
  • IIT JAM
  • Chemistry (CY)

In the complex [ni,(n5 - cp),(co),], the ir stretching frequency appears at 1857 cm (strong and 1897 cm-1 (weak). the valence electron count and the nature of t

In the complex [Ni,(n5 - cp),(CO),], the IR stretching frequency appears at 1857 cm (strong and 1897 cm-1 (weak). The valence electron count and the nature of the M-CO bond respectively are (A) 16e, bridging (B) 17er, bridging (C) 18e, terminal (D) 18e, bridging

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  • Parvathy

    sir electron counting where did that last 2 come from?

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    for metal-metal bond it is added

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    Priyanshu kumar best-answer

    Stretching frequency of terminal CO varies from 2143 to 1850 cm^-1 and the valence electron count is 2×10+5×2+2×2+2=36. means 18 electrons per metal.....so...oprionC is correct

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