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Nilanjan Bhowmick AIR 3, CSIR NET (Earth Science)
Dinesh khalmaniya 1 Best Answer
yes, absolutely right. here we will prefer ortho effect in benzoic acid as well as in aniline. ortho substituted benzoic acid is most acidic and Ortho substituted aniline is least basic due to steric reason
so in the option A, most basic is II due to ortho effect. in Option C most basic is I due to Ortho effect
in Option C and D we will check +I effect.
In Case Of benzoic acid, Due to + I effect acidity decrease because acidity is inversely proportional to +I effect so I>II
In case of option D, here we are talking about basicity of aniline and we know+I effect increase the basicity to ii>i
got it??
if any doubt you can ask me I'll be happy to help you.
yes sir sure
I got it sir