More stable the bond, the more is the bond energy na?

how

based on stability of carbocation

plz show how

stability order is benzylic > 3> 2> 1> sp2ch

more stable more bond energy na?

d is most stable coz of reso snd +I effect.

yes

so how your e is most stable.. it is least stable na coz of free radical on double bond

yes it is least stable among this

but you wrote e has most c-H bond energy

yes more stable less bond dissociation energy

why so.

check by homolysis bond cleavage

by considering free radical stability

Got this sourav??

but sir by that only i solved it.. my answer is coming in opposite order. can you check plz

okk wait

a becomes least stable na primary free radical

b tertiary free radical

c secondary

E has free radical on double bond

f benzyl free radical

d how double bond??

typing error

e should be least stable na.. coz free radical in double bond.

wait

sourav here free radical is resonance stabilised in case of e ..so most stable

how can this be reso stablised

sorry....benzyl one is reso stabilized

d should be most stable na coz of reso and +I effect.

order given is what e most and d least??

yes sir

order gets reversed by considering free radical stability

why sir.

sourav think agar bond tutne ke baad agar jyada instability aa jaye to wo bond tutna nhi chahega so hmko jyada bond energy lgana hoga bond break krne ke liye

so if it is gone towards instabilty then more bond energy required

when we consider e we have least stable free radical...so it require more bond energy

to check bond energy, remove the and check the stability of - charge

why - charge sir?

because, here after removal of H, negative charge obtained

because here we are checking strength of C-H bond, so we will check, the stability of carbanion

i thought we will check the strength of free radical

yes, you can check the stability of free radical also. results will be same because same factors such as resonance, inductive effect, affecte the stability of FR and Carbanion

sir but if im checking stability of - ve charge, answer is not coming. kindly check

yes, wait

d is most stable and e is least stable

how sir.

answer is e most stable d least stable

wait..

check it

Sourav more the stability of Free radical, less is the bond strength of C-H bond. because if H FR can is removed easily if the carbon FR is most stable

got it?

so least stable bond will have more bond energy?

here we will check bond dissociation energy of bond so we need homolytic cleavage

but sir we have learnt that more stable is the bond, more is the bond dissociation energy.

yes, but we will check it by the stability of FR na?? less stable the free radical more stable the bond??