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Reshav posted an Question
July 20, 2020 โ€ข 03:04 am 30 points
  • IIT JAM
  • Chemistry (CY)

Most stable chair form wil be

113 VWICIl 15 t 0St StaUie unau 1OLII OI Us COip0uid (c) ( (a) (b) Which of the followina malaauaa 10

2 Answer(s) Answer Now
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    Dinesh khalmaniya 1

    to solve this type questions, put bulky group at equatorial position and put the othere group according to relative position of it

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    got it Reshav??

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    1,2 cis - a,e, 1,2 trans a,a/e,e

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    1,3 cis- a,a/e,e , 1,3 trans - a,e

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    1,4- cis - a,e and 1,4- trans a,a/e,e

  • comment-profile-img>
    Priyanshu kumar best-answer

    Option B

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    jab bulky grp equatorial pe hoga to wo jyada stable hoga

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    samjhe reshav??

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    1,2 or 1,4 position me a,e or e,a cis hota

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    got reshav??

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    but isme ch3 1,3 diaxial interaction nhi krega

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    ok acha please tell me why option c cant be stable please give that reason? please

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    okk wait

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    wait by drawing i explain u

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    check reshav

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    got it i explained above...for 1,2 and 1,4 a,e or e,a cis hoga or 1,3 ke liye a,a or e,e cis hoga

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    any more doubt reshav??

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    no doubt thanku so much

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    welcome reshav๐Ÿ˜Š

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    i was just confused in stereo maintaining in ques and ans

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    please mark the answer reshav if it helps u๐Ÿ™

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    concept sara padh lijiye phle uske baad achhe se bana lijiyega

  • comment-profile-img>
    Dinesh khalmaniya 1

    hope this will help you ๐Ÿ™๐Ÿ™๐Ÿ™

  • comment-profile-img>
    Dinesh khalmaniya 1 Best Answer

    option B

    cropped3382811062526757718.jpg
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    got it??

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    but isme 1,3 diaxial interaction bhi hogi axial pe jo methyl hai usse

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    yes, axial methyl group show krega

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    discuss here Reshav. I'll be happy to help you. if you have any doubt you can share me

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    please tell why option c is incorrect as in that case both groups are at equatorial position and no interaction so that should be more stable why option b

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    let's check all the options

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    phle dekho cyclic structure me kya stereochemistry de rkhi he. yha 1,4 cis he to hmesa axial - equatorial position hogi

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    got it??

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    ab shyad aapko smjh aa gya hoga ๐Ÿ™

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    got it Reshav???

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    i was just confused in cis trans stereo

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    now its clear thanku so much sir g

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    you welcome ๐Ÿ™๐Ÿ˜Š

  • Suman Kumar

    Option B is correct

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    what is tge reasons and how to check stability in such questions

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    Reshav first note that stereo of both groups is above. Keeping this in mind fixed the stereo of bulky group in equatorial position.

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