Shrishty Turakhia posted an Question
September 06, 2020 • 21:30 pm 30 points
  • IIT JAM
  • Chemistry (CY)

Oi towet sitei cottuioule tatit1. electron group all higher groups same group group with (n - 1)|group with (n -2) 1s 0 0.30 0 0 ns, np 0.35 0.85 1.00 nd, nf 0.

OI TOWET SITEI COTTUIOuLE tatiT1. Electron group All higher groups Same group Group with (n - 1)|Group with (n -2) 1s 0 0.30 0 0 ns, np 0.35 0.85 1.00 nd, nf 0.35 1.00 1.00

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  • comment-profile-img>
    Priyanshu kumar Best Answer

    This is slater's rule for finding screening constant

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    what's your doubt in this?

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    see

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    please ask if any doubt

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    confused between distinguishing n, n-1,n-2

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    ourtmost shell is n...valence shell

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    n-1 is next inner to valence shell...that is penultimate shell

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    n-2 is anti penultimate shell

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    so for which electron you have to find screening constant accordingly you take n,n-1,n-2

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    now got dear student??

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    IN case of B we take 2s, 2p as n

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    yes

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    as if you have to find screening constant of p electrons in boron

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    but IN case of Ti we do not consider 3s, 3p

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    as n shell why

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    yes,first you have to make a grouping of these

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    done

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    1s, 2s,2p 3s,3p 3d like these

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    next

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    if you have to consider d electron for screening constant then n= the period in which that d electron lies

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    n-1 inner to that

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    n-2 next inner

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    see once my attached image...

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    3s, 3p as n-1

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    is it so

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    for d electrons ...only n is taken and all other lower orbitals shields same...but for s and p orbitals n-1,n-2 cases comes

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    D is considered as n

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    yes

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    okk tysm

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    you welcome😊

  • comment-profile-img>
    Dinesh khalmaniya 1

    what's your doubt??

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    I Am getting confused in Slater's rule even after learning the rules some questions are solved but most answers comes to be false

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    okay wait.. i think need to clear more concept

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    yes starting form ( n-2) and (n-1 )

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    check this video https://youtu.be/SXk43GQnETo

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    you can share your question so we can clear your doubt where your actually getting problem

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    okk

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    confused between distinguishing n, n-1,n-2

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