Shib Sagar posted an Question
September 19, 2020 • 17:50 pm 30 points
  • IIT JAM
  • Chemistry (CY)

Please solve this problem

eom prre he audie strrengh oman The aci ds COm pNTE HCoo

1 Answer(s) Answer Now
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    Priyanshu kumar Best Answer

    Ist one is most acidic here

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    oxalic acid is more acidic than malonic acid which is more acidic than succinic acid

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    No electron releasing methyl group in oxalic acid...one in malonic acid and 2 in succinic acid

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    sir how to solve this kind of questions

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    check for aromatic and antiaromatic system

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    stability of aromatic >non aromatic >antiaromatic

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    So if reaction leads to instability then it is not possible

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    sir here no cyclic ring is present and has no planarity how aromatic ka concert kasa lagega

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    cyclic ring to hai na...4 membered first me hai..cyclobutadiene...4 pi electrons antiaromatic

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    last me dekho...3 membered ring or conjugation bhi hai double bond or negative charge...so 4 pi electrons...antiaromatic

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    mujhe sir kuch v samaj nhi aa raha mujhe toh sir yaha acyclic compound he dikh raha hai

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    sorry shib i m explaining another ques explanation

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    sorry sorry

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    This is previous ques explanation

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    ok sir no problem now please solve this problem😊

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    Here you easily solve shib...methyl group electron releasing grp increase hone se acidity kam hota hai

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    oxalic acid me ek bhi methyl grp nhi hai....

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    sir i thought i should form anion between the two cooh grps and check the anion stability

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    yes this also you can check in case of malonic acid and succinic acid...active methylene grp hai malonic ke case me

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    so malonic jyada acidic hai succinic acid se kyunki carbanion stabilised honge two EWG se

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    but sir usaa mai oxalic acid ko kaha rakhu samaj nhi aa raha tha so

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    yha only cooh grp ..releasing nature to nhi hai na methyl ka...or carboxylate ion jyada stabilised hai or sabhi se

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    shib check all other queries too

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