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Nilanjan Bhowmick AIR 3, CSIR NET (Earth Science)
Priyanshu kumar Best Answer
Ist one is most acidic here
oxalic acid is more acidic than malonic acid which is more acidic than succinic acid
No electron releasing methyl group in oxalic acid...one in malonic acid and 2 in succinic acid
sir how to solve this kind of questions
check for aromatic and antiaromatic system
stability of aromatic >non aromatic >antiaromatic
So if reaction leads to instability then it is not possible
sir here no cyclic ring is present and has no planarity how aromatic ka concert kasa lagega
cyclic ring to hai na...4 membered first me hai..cyclobutadiene...4 pi electrons antiaromatic
last me dekho...3 membered ring or conjugation bhi hai double bond or negative charge...so 4 pi electrons...antiaromatic
mujhe sir kuch v samaj nhi aa raha mujhe toh sir yaha acyclic compound he dikh raha hai
sorry shib i m explaining another ques explanation
sorry sorry
This is previous ques explanation
ok sir no problem now please solve this problem😊
Here you easily solve shib...methyl group electron releasing grp increase hone se acidity kam hota hai
oxalic acid me ek bhi methyl grp nhi hai....
sir i thought i should form anion between the two cooh grps and check the anion stability
yes this also you can check in case of malonic acid and succinic acid...active methylene grp hai malonic ke case me
so malonic jyada acidic hai succinic acid se kyunki carbanion stabilised honge two EWG se
but sir usaa mai oxalic acid ko kaha rakhu samaj nhi aa raha tha so
yha only cooh grp ..releasing nature to nhi hai na methyl ka...or carboxylate ion jyada stabilised hai or sabhi se
shib check all other queries too