Simun Mishra posted an Question
July 17, 2020 โ€ข 18:24 pm 30 points
  • IIT JAM
  • Chemistry (CY)

Pls explain the structure b and c how can here n is sp2 ?

2 Answer(s) Answer Now
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    Reshav

    c is also sp2 hybridised as nitrogen is double bonded

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    c is not sp2 hybridised

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    it will be sp2 as nitrogen is double bonded

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    and double bonded nitrogen is sp2 hybridised

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    but N not in conjugation so the free l.p also count as singma so total sigma 4 and it will be sp3

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    but it has formed pi bond also

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    so we can say sp2

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    its answer given in the answer key is abcd please check

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    because i have already done this assignment

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    double bonded nitrogen atom is also sp2

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    but and is given wrong

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    concepts never wrong ....according to concept

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    no of sigmabond ...+ localised l.p = hybridisation

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    wait I will send u the pic

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    i agree concept never go wrong but in the goc lecture i have done same example in which it is said to be sp2 because it already formed pi bond

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    seee this ....

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    just wait

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    ok

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    please correct in your option b in your notes as boron have not empty d orbital it has empty p orbital

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    sry ...I will correct it

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    tell me clearly that c is sp2 or sp3

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    please check in the above two examples

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    please check

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    did you get it please tell me

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    yes ur correct here also 3 sigma possible another l.p which I m counting is not possible

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    now you understood completely or have any doubt

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    can u give me ans of 9.10 and 13 no question of this assignment pls ..

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    can u ..?

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    mesomeric always get priority over all other electronic effects in comparison of carbocation stability

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    but in q 10 all the c+ attached to +m group

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    no please check that in q10 in a and b carbocation is one carbon away from the lone pair containing groups for mesomeric it should be adjacent or dirctly attached to lp containing groups as in option b and d

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    sorry as in option c and d

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    in b no mesomeric is present

  • Suman Kumar best-answer

    Apply the same concept check if there is double bond adjacent to lone pair then it is sp2 hybridized

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    yes I apply this in case of b their is a free l.p so I told u that b is sp3

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    B is sp2 hybridized Simun

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    how can u explain by draw it

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    B has only 3 valence electron. So only 3 hybrid orbital will be there.

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    So I have no copy pen Now. Please understand.

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    sir the N in c is sp2 or sp3 ..?

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    sir c also 3 sigma so it is also sp2

  • Suman Kumar Best Answer

    Option A,D,B is correct

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    but the N in B is also a localised l.p also

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    4 sigma so sp3 in the B

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    In option B Boron has empty p orbital. If any lone pair is adjacent to p orbital then lone pair is also used for delocalization.

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    ohhhh I don't know about this so tqq ...โ˜บโ˜บ

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    ๐Ÿ™๐Ÿ™๐Ÿ™๐Ÿ™

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