Shweta Thakur posted an Question
October 05, 2021 • 03:51 am 30 points
  • IIT JAM
  • Chemistry (CY)

Plz anwer this..please respond noj this intramolecular rearrangement readily does not oceur tor (a) co (b) lr fcyc dp as

(NET/9ATE)(2021 CHEM ACADEMY Q IONH)MONO)F>|NH) MNOJ This intramolecular rearrangement readily does not oceur tor (a) Co (b) lr fcyC dP As

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  • Shreyasi majumdar 1 best-answer

    Correct option is d. Here Pt4+ preferentially interacts with O according to HSAB principle. So, intramolecular rearrangement would not be prefered

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    but the answer is c

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    The reason is correct (hsab). Pt4+ is soft. All 4d and 5d metal ions are infact soft. So, we will consider option a and c, out of which Cr3+ is hard and interacts with O (hard). So, correct option is c

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