Shweta Thakur posted an Question
August 21, 2020 • 02:22 am 30 points
  • IIT JAM
  • Chemistry (CY)

Plz explain 4th question... te +0, ()= co (g) at 298 k and 1 atm, ah =- 264lb if the molar

1S T44U ca 4U calories per mole t suue, find nd Au. 64Clfme (1440 cal 4/For the reaction, Cgraphite +0, ()= CO (g) at 298 K and 1 atm, AH =- 264lb If the molar volume of graphite is 0-0053 litre, calculate AU. -26712 cal 5. One mole of an ideal gas at 300 K expands isath 20 litres. Calculata

2 Answer(s) Answer Now
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    Priyanshu kumar Best Answer

    check this shweta👇

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    please ask if any doubt in this😊

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    Vfinal we calculate here shweta...as molar volume is 24.46 and change in number of gaseous moles =1-1/2=1/2

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    V initial of graphite is given to you

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    P is 1 atm and then calculate all these values

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    sir

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    graphite molar volume is given

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    yes shweta this is V initial reactant side

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    after completion at 298K and 1 atm..molar volume is 24.47(general)

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    we calculate Vfinal

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    change in gaseous moles * 24.47

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    got it?

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    22 .4 l sir

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    At 25°C and 1 atm 1 mole of gas occupies 24.47 molar volume

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    At 0°C and 1 atm it occupy 22.4L

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    sir

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    😊🙂👍

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    sir

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    am getting -3.458 kj sir ..

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    this is next question

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    okk let me check shweta

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    ok sir

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    shweta 2 ques is pending after answering this i will solve this and send you here

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    okay sir🙂

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    just tell me one thing

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    can I solve that 4 th question like this

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    shweta formula is right but ans is also not coming....here Volume is given you have to use formula in which volume is there

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    sir but m not getting why u have multiply Ng factor

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    there

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    for final process in finding V final

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    you took 25c in place of 298 k.. put it the eq. answer is coming to be 26714

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    sorry its dH = dE + dnRT

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    yes ..

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    thanks

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    sir

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    mai mail pe bhej deta hu

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    sir

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    sir

  • comment-profile-img>
    Dinesh khalmaniya 1 best-answer

    solution

    cropped2284951211878833232.jpg
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    got it??

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    what are the values of vfinal and v initial

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    app is not working well

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    DH = DE + PDV, in order to calculate DE we need to calculate PDV. The variation of volume is due both to the disappearance of solid graphite and to the variation of number of moles (1 - 1/2 = 0.5). Remembering that a mole of a gas at standard condition (0 oC and 1 atm) occupies 24.4 liters: DV = (0.5) (24.4) = 12.2 liter Thus the variation of volume due to the variation of number of moles is 12.2 and, by neglecting the variation of volume due to the disappearance of solid graphite (0.0053 liter), PDV = (1 atm)(12.2 liter) = 12.2 liter-atm Since 1 liter-atm is 24.4 cal,  PDV = (12.2) (24.4) = 297.68 cal DH = DE + PDV DE = -26416 - 297.68 = -26713 cal Alternatively and more simple, remembering that PDV = DnRT and that Dn = 0.5 PDV = 0.5 RT = (O.5)(1.987) (298) = 296 DE = -26416 - 296 = 26712 cal In this last case, care must be taken in the choice of R (here cal/mole deg).

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    here D = delta

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