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Shweta Thakur posted an Question
October 05, 2021 • 01:53 am
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30 points
30 points
- IIT JAM
- Chemistry (CY)
Plz explain this question... ular rearrangement readily does not occur for (a) co b) ir cec d) p ans
(NET/GATE)02202 eG 42C CMEM ACADEMY Q ONH,),MONO)((NH, ) M(NO )J This intramolecular rearrangement readily does not occur for (a) Co b) Ir CeC d) P Ans
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Shreyasi majumdar 1
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Correct option is d. Here Cr3+ preferentially interacts with O according to HSAB principle.(hard hard interaction) So, intramolecular rearrangement would not be prefered
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plz explain it more
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Cr3+ is a hard acid. When ONO is interacting then with O hard hard interaction is taking place. But if ONO changes to NO2, N being softer than O, hard soft interaction will take place which is not favorable
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Akash
hllo shweta Thakur, r u from karnataka
no