Shweta Thakur posted an Question
June 01, 2020 • 20:11 pm 30 points
  • IIT JAM
  • Chemistry (CY)

Plz explain this ... u calories of heat are absorbed by the system. the molar volumes of ice and ualer

U Calories of heat are absorbed by the system. The molar volumes of ice and Ualer are 0-0196 and 0-0180 litre respectively. Calculate AH and AE. Solution: Since AH = p bx. 5. When 1 mole of ice melts at 0°C and at constant pressure of 1 atm, heat absorbed by the system at constant pressure = 1440 calories. In the equ uation AH = AU + pAV pAV=76x 13.6 x 981 (18-19.6) ergs 76x 13-6 x 981 x 1-6 4-18 x 10 pAV is very small compared to AU, pAV can be neglected. calories p-1 atm 76 x 13-6 x 981 dynes, hus, AH= AU 1440 calories. =-0-039 calories. V2 = 18 cc, Vi = 19.6 cc) Snce

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    Lingareddy 1 best-answer

    pressure 1atm= 76 cm of hg(mercury ) Mercury (Hg)is 13.6 times denser than water acceleration due to gravity =981cm/s2

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  • Shweta thakur

    and sir plz answer my previous question also

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    yes, I'll check but please if you got it accept the ans

  • Shweta thakur

    and sir the question which I have sent u there in the solution they have convert work into calories by multiplying 13.6*76*981*volume in cc why

  • Shweta thakur

    and sir plz see my solution

    cropped3722739574142495153.jpg
    eduncle-logo-app

    your ans is different so please use simply method send by me

    eduncle-logo-app

    but I'm really appreciate atleast you are trying yourself 🙏

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    thanku sir

  • Shweta thakur

    why there is negligible work done here

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    work done is given by w = -pdv right? , here given that delta H = 1440 and we got delta U = 1439.97 so here work done will be delta U - delta H = 1440 - 1439.97 = .03 cal. it is very small quantity so we can neglected work done

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    so delta H = delta U

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    ok sir

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