Shweta Thakur posted an Question
September 28, 2020 • 02:30 am 30 points
  • IIT JAM
  • Chemistry (CY)

Plz explain what is the difference between p opposite and p2 in irrereversivle process's..... e gas involved is ideal, using pv = rt, we have rt

AlTerilau temperature T, as follows : From equations (23) and (24), (27) bu s C, (T2-T1)=- Popp (V2- V,) As the gas involved is ideal, using PV = RT, we have RT, T7 227 RT VP and V2P RT RIT P Substituting these values in eqn. (27), we get RT2 RT C (T-T) =opPP .(28) or C, (T2-T)=- Popp P2 Taking Popp= P2, i.e., the pressure of the gas after expansion, we get RT RT, .(29 C,T-T)=2P PB wOyoautu C,T2-C,T=2-RT, or C,T + RT=C,T +2 P RT or P RP2 C+R) T2 = T or P RP2 C,Ta =TC+ or P C+RP2/ P Ta T or Cp

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    Priyanshu kumar Best Answer

    Popp is external pressure and it is denoted also as Pext...For a special case Pext=P2 where P2 is the pressure of gas after expansion. When Popp not equal to P2 then you have to use equation 28 for calculation

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    sir

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    ye kya SB delete ho gya

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    sir mane ye poochna tha ki... p opposite = p external ye possible ho skta irreversible process main reversible main to Hoga hi ni

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    haa

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    pext or Popp=P2 special case me hoga

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    mtb kya special

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    jb given ho ques me tbhi lena hai

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    nhi given ho to equation 28 tak hi use karna hai

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    ques dekho

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    sir ye b part main pressue to Diya ni

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    haa maine bheja ye ki dekho mention kiye honge

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    sir PV = nrt se aa jayega because constant pressure ke against expansion hain to irreversible process Hoga to Jo final volume hai 48.4 ke aspect main pressure nikl lija

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    Dekho aab

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    haa or P2 or Pext same ho jayega

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    Shi hai n aise find out krna hai n

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    haa👍

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