Sahiba Naqvi posted an Question
April 02, 2021 • 17:51 pm 9 points
  • IIT JAM
  • Chemistry (CY)

Sir in case of eg3 zin dominates or zout dominates

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  • Achyut ranjan gogoi

    zout dominates in eg3/eg1. zin dominates when electron is in t2g1/t2g4

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    Sir, plz explain how zout dominates in eg3

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    Elongation occur when the degeneracy is broken by the stabilization (lowering in energy) of the d orbitals with a z component, while the orbitals without a z component are destabilized (higher in energy) 

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    This is due to the dxydxy and dx2−y2dx2−y2 orbitals having greater overlap with the ligand orbitals, resulting in the orbitals being higher in energy.

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    Dinesh khalmaniya 1

    d1, d4 and d6 zin dominated. check the configuration first. in case of Oh complex eg gives strong JTD and T2g gives weak JTD. And vice versa for Td complexex.

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