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Nilanjan Bhowmick AIR 3, CSIR NET (Earth Science)
- IIT JAM
- Chemistry (CY)
Solvolysis of the optically active compound x gives, mainly: meo mc acok acoh ots me a) meo me oa me opiically active) b) mco me oac me (oplically activ ) c) me
Solvolysis of the optically active compound X gives, mainly: MeO Mc AcOK AcOH OTs Me a) Meo Me OA Me opiically active) b) McO Me OAC Me (oplically activ ) c) Meo Me OAc Me oplically inactiv) (Raceic d) MeO Me OAc Me (oplically mactiv c (Racemic
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Priyanshu kumar
Option C is correct Explanation:- -OTS is a good leaving group. So after departure of the leaving group (OTS-) a carbocation will form whose geometry is planer so there is two possibility of attacking the nucleophile ( OAC- furnished by AcOK) : 1) above the plane and 2) down the plane . So a racimic mixture will be formed which is optically inactive. If the nucleophile attacked the carbon centre from down the group then the configuration of the centre will either of the + or - then the racimic mixture was not obtained .
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Suman Kumar
option C is correct. Sn gp mechanism