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Divya posted an Question
September 25, 2020 • 23:18 pm 30 points
  • IIT JAM
  • Chemistry (CY)

Stability in cyclohexane

Sir in twist boat form all strains are absent then why it is less stable than chair form in cyclohexanes

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    Priyanshu kumar Best Answer

    There is still some torsional strain in twist boat form

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    The boat conformation of cyclohexane is not a very stable form due to the torsional strain applied to the cyclohexane molecule. ... Owing to these factors, these conformations are generally converted into twist-boat forms which have a lower torsional strain and steric strain in them.

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    sir that means some lower strains are present in twist boat form which makes TWIST BOAT form less stable than CHAIR form and more stable than TRUE BOAT form.Right

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    yes here vanderwaal strain which comes from flagpole interaction in boat is relieved in twist boat but still little amount of torsional strain

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    So chair is most stable

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    yes sir now clear.sir one more

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    yes

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    sir in this plane of symmetry exists or not

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    Twist boat is chiral as it lacks plane of symmetry not boat

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    In boat there is C2 axis of symmetry

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    sir if we pass mirror through the centre of the molecule can't the molecule form mirror images

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    when you view through like rotating model type...you see axis of symmetry

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    only twist boat lacks plane of symmetry

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    sir that means the two ring structures are arranged perpendicularly

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    hence no sigma got it sir.

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    sir can you provide video regarding REACTION MECHANISM

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    for specific which part ?

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    nuclephilic substitution sir

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    okk wait let me check

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    https://youtu.be/BRBLa1xX9K8 check this

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    bdw good video are not available in English version..

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    You can read from peter sykes book for mechanism part...best book

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    ok sir I will read.Always grateful to you sir

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    study more and more.😊👍

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    sir can you recommend any book for practicing bits

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    For organic?

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    yes sir

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    when you complete any chapter practice questions from chem academy questions bank...Sufficient for jam...Good and sufficient questions are there

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    sir does physical also available here

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    yes

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    https://drive.google.com/folderview?id=1FaKkGNXSa7XffyEgRmyw2Zkz7sImXV0C check

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    sir really so many bits.excellent

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    Always thanks for your time and help sir.

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    welcome😊👍

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    Sir can you video for the topic FUNCTIONS (maths) in the part of jam

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    sir can you send me the video

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    https://www.youtube.com/playlist?list=PLWPirh4EWFpETnJg0qMWuEGPdH68FecPg see this playlist

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    Sir for remaining topics also can I go through this

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    yes for mathematics part in jam read from this selectively according to syllabus

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    ok sir .Thank you so much sir.

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    welcome 😊

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