Roni posted an Question
February 01, 2022 • 13:19 pm 30 points
  • IIT JAM
  • Chemistry (CY)

What is prelog interaction . .... in opption d

what is prelog interaction . .... in opption d..........

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    Lingareddy 1 Best Answer

    In organic chemistry, transannular strain (also called Prelog strain after Nobel Prize–winning chemist Vladimir Prelog) is the unfavorable interactions of ring substituents on non-adjacent carbons. These interactions, called transannular interactions, arise from a lack of space in the interior of the ring, which forces substituents into conflict with one another. In medium-sized cycloalkanes, which have between 8 and 11 carbons constituting the ring, transannular strain can be a major source of the overall strain, especially in some conformations, to which there is also contribution from large-angle strain and Pitzer strain In larger rings, transannular strain drops off until the ring is sufficiently large that it can adopt conformations devoid of any negative interactions.

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