Simun Mishra posted an Question
July 14, 2020 β€’ 20:51 pm 30 points
  • IIT JAM
  • Chemistry (CY)

What is syn and anti periplanar

2 Answer(s) Answer Now
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    Dinesh khalmaniya 1 Best Answer

    check it to understand stereochemistry of E2

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    please accept the answer if you got it πŸ™πŸ™

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    in case of E1 any syn or anti addition occurs or not

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    no, here carbocation is formed

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    so only in e2 case anti elimination occurs

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    yes

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    syn mean bond angle between H and Lg is 0 and anti mean bond angle between H and LG is 180

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    got it??

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    so in case of e2 syn elimination can't occur

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    yes, here anti elimination takes place

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    only Cope elimination gives syn elimination

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    cope elimination means

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    The β€œCope Elimination” is a reaction where an amine is oxidized to an intermediate called an β€œN-oxide”, which, when heated, acts as the base in anΒ intramolecularΒ elimination reaction.

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    syn elimination

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    got it??

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    how many types of eliminations are their ...

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    E1,E1cb,E2, cope elimination

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    so cope also under goes in this elimination type ..?

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    yes, it's the part of elimination reactiona

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    It is also known as Ei elimination

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    i think you have heard about Ei

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    ok pls ...explain those lines which I m attached with why questions why here mention syn periplanar

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    wait..

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    like intermolecular substitution sni ei ...is same or not ?

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    SNi and Ei is different things

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    here they are only telling that elimination occur via syn or anti manner but it doesn't mean they say that E2 is syn and anti both. E2 is only anti elimination

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    so why mention syn periplanar

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    they tell only tpe of elimination syn or anti

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    ohhh ...ok

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    got it😊??

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    one little doubt

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    yes, please

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    I know sni and Ei are different just I m saying that sni is intermolecular substitution and Eni is intermolecular elimination ..in these way I m saying it same

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    can u give ur video lectures...?

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    yes, Ei mean internal elimination just like SNi

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    yes, https://youtu.be/cVlM74yhzYA

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    please mark the answer if you really satisfied with my way to explanation.

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    I m not asking about this lectures I m asking about ur video lecture

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    no, I don't have my video lecture

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    ohhh but ur way of explanation is so helpful ..if u do any video lectures it must be very much helping ...πŸ™πŸ™

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    yes, I'll provide you πŸ™

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    tq very very much for this kind helping...πŸ™πŸ™

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    it is intra or inter in case of cope elimination

  • Suman Kumar best-answer

    E2 elimination happen from antiperiplanar. Cope elimination is syn elimination.

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    Dihedral angle should be 180⁰ in anti periplanar

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    Simun do you know dihedral angle ? We use this in newmann

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    See this anti periplanar

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    See this. Dihedral is zero for syn elimination

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    what is dihedaral angle

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    Newman conformation do know?

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    yes

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    but in case of e2 elimination only anti elimination occurred so why here syn elimination

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    Syn elimination termed as Ei not E2

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    E2 is always anti periplanar

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    https://youtu.be/d2i3uU_s1XU. For dihedral angle. Short video. see it

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    but the image I attached with my question is written both syn and anti periplanar

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    can u explain those lines which are written in the image ..

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    I was checking Simun

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    Which book is this Simun?

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    E2 is anti-periplanar only Simun. In the image it is written that elimination can happen in two ways.

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    I have provided explanation Simun

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    Simun any more question?

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    can u provide u r video lectures also or not ??

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    Ofcourse Yes. Please say your topic

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    about chemistry of reactive intermidiate

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    and can u give ur video lecture for organic for imp ...for jam pls pls ...πŸ™πŸ™πŸ™πŸ™πŸ™the tricks the basics ...

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    Simun chem academy providing free lecture for IIT JAM. please watch that

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    can u give me link of this

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    r u from chem academy

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    yes Simun

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