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In Na2SO4, sodium acts as the cation with the sulphate anion which means that they share an ionic bond, while the sulphur and oxygen atoms in sulphate are covalently bonded.
Sir Ni(CO)4 contains covalent C=O and ionic bond with Ni4+, so why it will not be answer?
Ni is neutral here.. and the bond between Ni and CO is co-ordinate.