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Reshav posted an Question
June 12, 2020 • 00:28 am 30 points
  • IIT JAM
  • Chemistry (CY)

Which of the following compounds has the most acidic o-hydrogens? o c-chs a. (a) hc chs b.(b) o ch-0-Č-ch3 c.(c) o o ch-0-ë -ch3 c.(d) o h l hc-c-c c-ch

Which of the following compounds has the most acidic O-hydrogens? O C-CHs a. (A) HC CHs b.(B) O CH-0-Č-CH3 c.(c) O O CH-0-ë -CH3 c.(D) O H l HC-C-C C-CH

3 Answer(s) Answer Now
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    Shivaji khadake

    hello student Acidity mainly will be identified on "pka" value of that proton. if pka value lesser then compound will more acidic in nature. so you have to compare pka value of all the compound. a) 20 b) 25 c) 11 d) 9 so now you can easily identify that the compound (d) has lesser pka value because that middle carbon having adjacent to two carbonyl group which increase the acidity of middle carbon. out of this all compounds acetylacetone having lesser pka value so that compounds Alpha proton will be acidic in nature compared to all.

  • Suman Kumar

    A has ketone as Eletron withdrawing group. B has ester as Eletron withdrawing group but Ketone is more eletron withdrawing

  • Suman Kumar

    Compound C & D are active methylene compound. They most acidic due to Eletron withdrawing on both side.

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    Dinesh khalmaniya 1

    negative charge is highly stabilized by two ketonic groups

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    Lingareddy 1

    c option midlle hydrogen due to hylerconjucation

    eduncle-logo-app

    u are going protan nmr the protan in btw the two carbonyl compounds will be appeared at 3-4ppm

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