Manisha posted an Question
January 10, 2021 • 16:26 pm 30 points
  • IIT JAM
  • Chemistry (CY)

Which of the folowig will be on straight hne on lattice cnergy curve (b) sef, fef, gaf, znfs d) sor mnf, zofy a) scfs, mnf, fef scf fef, gaf heoretical value of

Which of the folowig will be on straight hne on lattice cnergy curve (b) SeF, FeF, GaF, ZnFs d) SoR MnF, ZoFy a) ScFs, MnF, FeF ScF FeF, GaF heoretical value oflH

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    Dinesh khalmaniya 1 best-answer

    option C. here Sc3+ (d^0), Fe3+ (d^5) and Gd3+ (d^0) has symmetric distribution of electrons so will be on straight line in the lattice energy curve. Check this reference https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Modules_and_Websites_(Inorganic_Chemistry)/Crystal_Field_Theory/Thermodynamics_and_Structural_Consequences_of_d-Orbital_Splitting#:~:text=Like%20hydration%20energies%2C%20lattice%20energies,indirectly%20from%20a%20thermochemical%20cycle.&text=The%20shape%20of%20the%20lattice,lying%20on%20the%20smooth%20curve.

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    Priyanshu kumar best-answer

    Option C.. These are having similar CFSE value https://youtu.be/eU9c3JMHlAA check this video for whole concept

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