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Sourav posted an Question
August 26, 2020 • 18:55 pm 30 points
  • IIT JAM
  • Chemistry (CY)

Which one is correct.. according to me first product is correct

2 Answer(s) Answer Now
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  • comment-profile-img>
    Dinesh khalmaniya 1 best-answer

    CH3 shift is correct. because in first step H+ attack on those OH group, which on leaving gives most stable carbocation. here carbocation is stabilized by two ph group

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    now we will check migratory aptitude

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    hope this will help you 🙏🙏

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    yes, CH3 shift is correct according to migratory aptitude

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    here CH3>H migratory aptitude

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    please accept the answer if you got it thanks

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    sir from which book you took the migratory order.. some are saying different order too..Kindly check and reply plz.

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    i got it from internet.

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    https://youtu.be/x52DBgwOlcQ

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    sir plz check it

  • comment-profile-img>
    Priyanshu kumar

    both are possible but H shift probability is more..so 1st is major

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    you get both product

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    got this??

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    sir this is migratory aptitude.

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    yes sourav migratory aptitude

  • Suman Kumar Best Answer

    H- shift is correct

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    For example, relative migratory aptitudes for alkyl substituents is Hydride >(CH3)3> Phenide >C2H5 > CH3.[2]

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    ya but in answer ch3 shift was done and given as product.. so i was confused

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    Last para

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    migratory aptitude is experimentally determined. So it is different for different reaction

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    sir for bayer villiger and pinacol pinacolone, are mig apt same?

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    mostly same. Again I am saying it is different from different reaction. You will have to consult standard text book like clayden.

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    i will send the order in the evening. please remind me

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    what about this? this says mig apt of Ch3 is more than H

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    please ask him the Full text.

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    for which reaction it is ?

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    sir check it is saying pinacolone rearrangement on the pic

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    verification book se hi hoga. I am sending you the reference of standard book

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