Shweta Thakur posted an Question
October 05, 2020 • 02:00 am 30 points
  • IIT JAM
  • Chemistry (CY)

Why alkyl group have + i effect

why alkyl group have + I kkjklk jjjkkmmkjnn bkm effectvhhvgjhjjljhjkhkbh jjo

2 Answer(s) Answer Now
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  • comment-profile-img>
    Dinesh khalmaniya 1 best-answer

    got it??

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    sry for the late reply

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    sir

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    can u explain it more

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    acha kya smjh me nhi aya..

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    simple he alkyl group SP3 hybridised hota he so %s characters km hoge

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    or jb koi double bond or EWG alkyl group se juda ho to EWG easily electrons ko pull kr lega

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    vhi baad he ki do groups jinki EN different he, to e usi k pass jayege na jiski jada hogi

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    sir

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    got it??

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    wait sir

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    carbon atom in alkyl group has higher electron density as compared to hydrogen

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    so it will donate the electrons simple

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    yes, but yha hm H or C k bich k baat nhi kr rhe.. yha dekhna ye he ki alkyl group kisse juda he.

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    check this...

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    check it

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    yhan ch3 aur c Ka dekhna

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    inductive effect hmesha comparison me dekha jata hw

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    right

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    mane Jo reason btaya tha vo Shi to hai

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    Jo aap keh re ho s character km hoga I agree

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    mtb. electronegativity of ch3 is low as compared to c 🤔

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    smjho baat ko inductive effect kb dekhte he jb acidity dekhni ho ya stability

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    is case me dekho, yha positive charge electrons ko pull krega to CH3 electrons donation krega i.e., +I

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    ok

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    I got it sir aap Jo keh re ho

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    last point dekho,

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    alkyk group isliye +I show krta he bcoz isse judne wala group generally high EN wala hi hota he

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    ok

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    thanku sir

  • comment-profile-img>
    Dinesh khalmaniya 1

    In short, alkyl groups tend to give electrons, leading to induction effect. so all alkyl group have +I effect

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    In alkyl group we have single bond means .. Sp3 (hybridisation) means there are 25%(100/4 as 1 s orbital and 3 p orbital) s scharacter , we know that less s character means less electronegative ( due to closeness of s character with nucleus) means think like if more s character at the nucleus what will happen it want to decrease that s character and become more electronegative.. Due to less electronegativity of alkyl group ,it gives electron very easily .. so act as a electron releasing group.. NOTE - In some case like grignard reagent (CH3-Mg-Br) , it acts as a electron withdrawing group , CH3- groups takes electron from Mg metal..

  • comment-profile-img>
    Priyanshu kumar Best Answer

    Alkyl group tends to donate electrons so +I effect

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    why

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    The alkyl group doesn't literally "push" the electrons away - the other end of the bond attracts them more strongly. This means that the alkyl group becomes slightly positive ( +) and the carbon they are attached to becomes slightly negative ( -). The alkyl group has a positive inductive effect.

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    sir

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    alkyl group carbon se to attach rehta

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    here electronegativity concepts also works

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    I m not gettting

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    wait

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    carbon is slightly more electronegative atom than hydrogen. hence, the carbon atom in alkyl group is higher electron density around it compare with hydrogenAs a result of that alkyl groups are able to donate electrons inductively when it attached with a pi system.

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    now got?

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    pi system kyun

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    hain

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    in general it has more electron density around it so it tends to donate electrons

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    thanky

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    sir

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    sir

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