Simun Mishra posted an Question
July 14, 2020 โ€ข 21:43 pm 30 points
  • IIT JAM
  • Chemistry (CY)

Why e2 reaction is sterio selective ?

2 Answer(s) Answer Now
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  • comment-profile-img>
    Dinesh khalmaniya 1

    hope this will help you ๐Ÿ™๐Ÿ™๐Ÿ™

  • comment-profile-img>
    Dinesh khalmaniya 1 Best Answer

    check these images for more details about stereoselectivity of E2

    cropped4072177244518203298.jpg
    cropped8364683457226965886.jpg
    cropped2822304961521841699.jpg
    cropped6444809492229362548.jpg
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    check this material which may help you to understand this topic very much

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    Thank you Simun๐Ÿ˜Š๐Ÿ˜Š

  • comment-profile-img>
    Priyanshu kumar

    check this simun...any doubt in this then ask?

    cropped3277484206345163947.jpg
    cropped7419701573857750061.jpg
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    here one products predominates over other..more stable product is formed inwhich anti conformation is present

  • Simun mishra

    means from syn and anti ...product anti is the major so

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    no, simun.. here we will talk about only anti products. if two antipriducts are possible then one will be major

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    check it

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    in this picture the Hb is in dash ...and br is also in dash so here antiperiplanar structure how possible

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    pls help in this ...

  • Simun mishra

    means the anti product ...

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    yes, but only one Anti product is possible then it is known as stereospecific but more than 1 anti products are formed then there is one product major so it is known as stereoselectivity

  • comment-profile-img>
    Dinesh khalmaniya 1 best-answer

    because here only one product is formed as a major product

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    can u give ur video lecture about Ei ...

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    yes, wait

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    ok

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    check it https://youtu.be/_iXlIUJykLY

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    I m not asking about this asking about ur video lecture

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    No, I don't have my own video

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    ok sry

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    check it

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    here two antiperiplanar elimination is possible but only one product is major

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    got it??

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    no

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    okay tell me what is your doubt so i can help you

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    first of all try to understand what is stereoselectivity. stereoselectivity simply mean if in a reaction if more than one products are formed and out of all the products only one product is formed as a major and another remaining products will be minor. this is the stereoselectivity. if in a reaction, only one product is formed so it is stereospecific

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    got it simun??

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    yes ...perfectly I got it ...tq

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    now same case in E2, if there is two antiperiplanar alpha H is present then there is possible to form two products. so out of two one will be major

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    now check this image,

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    hope you will get it..

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    please accept the answer ๐Ÿ™๐Ÿ˜Š

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    I m asking a question in my comment pls solve this

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    yes

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    can u find my question

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    no, i didn't get it. you can share it in new query so we can discuss properly

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    the image u send ..in this ..br and hb are in dash ....so how it will be anti periplanar to each other ..?

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    wait..

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    ok

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    convert it to newman conformation so you can get the answer

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    please mark my answer as best if you really satisfied ๐Ÿ™๐Ÿ™ I'll be happy to help you

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    when it converted to fisher projection then the ha and Br are in same side so how it will be anti periplanar

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    no, simun don't solve it using fisher formula because it is eclipsed conformation. you have to change it newman

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    ok

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